Hi,
Can you please further explain your query.
In order to use ASR with VMWare, a prerequisites will be access to VCenter and ESXi servers.
https://azure.microsoft.com/en-us/documentation/articles/site-recovery-vmware-to-azure/
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VMware
A VMware vCenter server managing your VMware vSphere hypervisors. It should be running vCenter version 5.1 or 5.5 with the latest updates.
One or more vSphere hypervisors containing VMware virtual machines you want to protect. The hypervisor should be running ESX/ESXi version 5.1 or 5.5 with the latest updates.
VMware virtual machines should have VMware tools installed and running.
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But, if you want just to protect/Replicate a VM, without having access to the hosts, you can consider it as a physical machine, and protect it. You will find guidance on the same link