Create a new Policy, go in to User Configuration, Choose Preferences, go to Windows Config, Drives, and create a new Mapped drive. Thats it.
http://blogs.technet.com/b/askds/archive/2009/01/07/using-group-policy-preferences-to-map-drives-based-on-group-membership.aspx?Redirected=true
First of all this folder must be shared folder and permissions must be configured for users
Goto Group Policy create Group Policy object. rename it, Goto user configuration--> Preferences -->Drive maps-->>At the right side Right click mouse click to New-->> Mapped drive
Select the folder to want to map from shared location
Select the Letter you want to assign to mapped folder and check the Reconnect.
After all settings link this Group Policy Object to OU which you want to apply.