Hi Vincent,
As Time synchronization that is based on a domain hierarchy uses Active Directorys domain hierarchy to find a reliable source with which to synchronize time.
Based on domain hierarchy, the Windows Time service determines the accuracy of each time server. In a Windows Server 2003 forest, the computer that holds the primary domain controller (PDC) emulator operations master role, located in the forest root domain, holds the position of best time source.
The simply way to make the second domain controller as the authoritative time server in the domain is that: you may transfer the PDC emulator role to the second domain controller from the primary domain controller that you want to decommission.
Please refer to:
How to view and transfer FSMO roles in Windows Server 2003
http://support.microsoft.com/kb/324801How to view and transfer FSMO roles in the graphical user interface
http://support.microsoft.com/kb/255690Hope it helps.David Shen - MSFT
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