Hi thekernel99,
To export multiple mailboxes to their respective .pst files at once you can pipe in the identities of those mailboxes to the export task. You don't need to open multiple instances of Powershell.
For example:
Get-Mailbox -OrganizationalUnit Marketing | Export-Mailbox -PSTFolderPath C:\PSTFiles
For more information,please see:
Export-Mailbox
http://technet.microsoft.com/en-us/library/aa998579(v=exchg.80).aspxFrank Wang
TechNet Community Support
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