Hi,
I don't know a direct way to realize this via GPO, but a workaround may be helpful.
Since the path for all users should be the same(C:\Program Files\Microsoft Office\Office\Winword.exe), we can make one shortcut, then modify its Properties -> Add
/n to the target behind the full path C:\Program Files\Microsoft Office\Office\Winword.exe. It will be like "C:\Program Files\Microsoft Office\Office\Winword.exe" /n
in the shortcut properties, save it to a shared folder, then create a startup script which pulls this shortcut from the shared folder to the user's local desktop.
Since I'm not a script expert, you may need to contact other resource for further assistance.
Regards,
Melon Chen
TechNet Community Su