Hi,
I agree with Michael, please check whether you created a A record for autodiscover service and pointed to the 2013CAS server.
In Exchange 2013 server, please run the following command to check your autodiscover service settings:
Get-ClientAccessServer | FL Identity,AutodiscoverServiceInternalUri
We can set the autodiscover by running the below command:
Set-ClientAccessServer -Identity CAS2013 -AutodiscoverServiceInternalUri https://autodiscover.domain.com/autodiscover/autodiscover.xml
Best Regards,
David