There is no report on this since it is something that is always being re-evaluated when clients request content - They are not 'assigned' to a boundary location (although they are 'assigned' to a site, but that's different). A report would only show historical
information, not live, so it wouldn't really be useful. If you are just trying to see in general what DP's people are using, you can use the report called "Distribution Point Usage Summary".
If you want to see a best guess of boundary and boundary group information for a workstation, you can use the
Now Micro Right Click Tools to show boundaries/boundary groups a workstation currently is in. For an individual client, right click and select Client Tools > Client Information and switch to the Boundaries
tab.
I hope that helps,
Nash