Hi RonJohnMsu,
For your issue, I would like to collect the following information:
There is no people picker in SharePoint 2013, Have you custom form with InfoPath?
Could you offered a screenshot about the People Picker Windows?
Do you mean that the issue only exists in IE 10?
You can use compatibility mode to check whether it works:Open IE->Tools->Compatibility View Settings
You can also add the site into Trusted sites: Open the IE->Internet Options->Security->Sites->add the site into the Websites, then check whether it works.
Whether the issue exists in other list/library?To force IE 10 to use standard:
http://techathlon.com/internet-explorer-10-run-compatibility-mode/
Feel free to reply back.
Best Regards,
Lisa Chen
Hi RonJohnMSN
Have your issue been solved?
Best Regards
Lisa Chen