does anyone know if this is possible? I wouldn't think so, but I figured I would check.

Not possible. The password is *not* stored anywhere. The best you could do is use a tool to set the password and then store what the tool set the password to. This would be something custom and would have security implications.

If you are looking to manage local admin passwords you should check out a recently released tool from Microsoft called Local Admin Password Solution: https://www.microsoft.com/en-us/download/details.aspx?id=46899

Lieberman software also has solutions/products for managing local passwords: http://www.liebsoft.com/

The Leiberman product looks pretty cool. I'd never heard of that one.