Well if you want to test software installation it would be good to test more than simple MSI.
MSI are probably the easiest of all the install. i would go with Java this will teach you out to extract a MSI from a EXE.
You could do a simple exe like notepad ++
you could try with adobe reader using the transform to get a exe + MSP
I would also test out a script to install a software and maybe copy some config file and change some reg key.
Also a good one is something like office 2013 very common and teaches you to do a config file and a admin file.
This is not really the answer to your question just my opinion people focus on MSI to often and forget not everything is a MSI and not everything can be converted to MSI. Some time you will get software that require a lot of touch after copying files over
changing some reg key and so on. So please test with all of the above and will give you a good start.
All the software above all have plenty of nice tutorial on the web for them.
Also a good site to start out is http://www.itninja.com/.
Hope this help
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Proposed as answer by
Jason SandysMVP
5 hours 2 minutes ago