Hi man,
I assume you are using SharePoint Client People Picker
You can actually perform the following JavaScript
EnsureScript("autofill.js", 'undefined', function() {
SPClientPeoplePicker.SPClientPeoplePickerDict.ctl00_PlaceHolderMain_peoplePicker_TopSpan.EnsureAutoFillControl();
SPClientPeoplePicker.SPClientPeoplePickerDict.ctl00_PlaceHolderMain_peoplePicker_TopSpan.AutoFillControl.AutoFillMinTextLength = 5
});
Just make sure you change the
ctl00_PlaceHolderMain_peoplePicker_TopSpan
to the correct people picker Id (it always ends with "_TopSpan", somehow) that you want to configure the min length for auto suggestion.
Hope it helps!